Interatomic potentials of cadmium-argon B1(3Σ+) and X0+(1Σ+) states based on near-dissociation expansion and ‘hot’ bands observed in the B1←X0+ excitation spectrum
Identifieur interne : 000392 ( Main/Exploration ); précédent : 000391; suivant : 000393Interatomic potentials of cadmium-argon B1(3Σ+) and X0+(1Σ+) states based on near-dissociation expansion and ‘hot’ bands observed in the B1←X0+ excitation spectrum
Auteurs : J. Koperski [Pologne] ; Sz.M Kiełbasa [Pologne] ; M. Czajkowski [Canada]Source :
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy [ 1386-1425 ] ; 2000.
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Abstract
B1(3Σ+)←X0+(1Σ+) excitation spectrum of the cadmium-argon van der Waals molecule has been recorded in the experiment of a continuous supersonic molecular beam crossed with a pulsed dye laser beam. The B1-state dissociation energy was directly observed and a long-range behavior of the B1-state intermolecular potential was derived using a near-dissociation expansion procedure of LeRoy and Bernstein. A first-time direct determination of the X0+ ground state characteristics based on ‘hot’ bands observed is presented as well. The new result is compared with other experimental and theoretical reports available in the literature.
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DOI: 10.1016/S1386-1425(00)00213-4
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The B1-state dissociation energy was directly observed and a long-range behavior of the B1-state intermolecular potential was derived using a near-dissociation expansion procedure of LeRoy and Bernstein. A first-time direct determination of the X0+ ground state characteristics based on ‘hot’ bands observed is presented as well. The new result is compared with other experimental and theoretical reports available in the literature.</div></front></TEI><affiliations><list><country><li>Canada</li><li>Pologne</li></country></list><tree><country name="Pologne"><noRegion><name sortKey="Koperski, J" sort="Koperski, J" uniqKey="Koperski J" first="J" last="Koperski">J. Koperski</name></noRegion><name sortKey="Kie Basa, Sz M" sort="Kie Basa, Sz M" uniqKey="Kie Basa S" first="Sz.M" last="Kiełbasa">Sz.M Kiełbasa</name><name sortKey="Koperski, J" sort="Koperski, J" uniqKey="Koperski J" first="J" last="Koperski">J. Koperski</name></country><country name="Canada"><noRegion><name sortKey="Czajkowski, M" sort="Czajkowski, M" uniqKey="Czajkowski M" first="M" last="Czajkowski">M. Czajkowski</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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